Q32 / 213 · NTA Abhyas (NEET) 2020 · Chemistry · s Block Elements

Which of the following statement is incorrect?

  • A
    The solutions of alkali metal in liquid ammonia are strongly reducing in nature
  • B
    BeCl2 is a linear molecule in vapour phase, but is polymeric in solid state
  • C
    Calcium carbide reacts with water to give acetylene
  • Correct answer
    D
    Calcium is also an essential constituent of chlorophyll

Solution

Here statement in option D is incorrect as Chlorophyll is complex of Mg and not of calcium.
A. Alkali metal solution in ammonia is strongly reducing, due to the presence of solvated electrons. Metal ammonia solution also liberate H2 on standing.
B. Anhydrous beryllium chloride is polymeric in solid state, but BeCl2 vapour contains BeCl2 and (BeCl2)2 . This compound exhibit three-centre bonding.
Figure
C. CaC2+2HOH→CH≡CH+Ca(OH)2

Hence, the correct answer is option: 'D'.

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