Q27 / 180 · KCET 2017 · Chemistry

Which of the following statement is in accordance with the Arrhenius equation?

  • Correct answer
    A
    Rate of a reaction increases with increase in temperature
  • B
    Rate of a reaction increases with decrease in activation energy
  • C
    Rate constant decreases exponentially with increase in temperature
  • D
    Rate of reaction does not change with increase in activation energy

Solution

According to Arrhenius equation
\[ k=A e^{\frac{-E_{s}}{R T}} \rightarrow(1) \]
Taking log of Eq. (1), we get
\[ \ln k=\ln A-\frac{E_{a}}{R} \times \frac{1}{T} \]
It is clear from the above equation that by increasing the temperature and by decreasing activation energy, the rate of
reaction will increase.

Hence, the correct answer is option: 'A'.

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