Q55 / 200 · NEET 2024 (Re-NEET) · Chemistry

Which of the following pairs of ions will have same spin only magnetic moment values within the pair? A. $\mathrm{Zn}^{2+}, \mathrm{Ti}^{2+}$ B. $\mathrm{Cr}^{2+}, \mathrm{Fe}^{2+}$ C. $\mathrm{Ti}^{3+}, \mathrm{Cu}^{2+}$ D. $\mathrm{V}^{2+}, \mathrm{Cu}^{+}$ Choose the correct answer from the options given below

  • A
    C and D only
  • B
    A and D only
  • C
    A and B only
  • Correct answer
    D
    B and C only

Solution

Magnetic moment $\mu=\sqrt{n(n+2)} B M$ $\mathrm{n} \Rightarrow$ Number of unpaired electrons Figure
Hence $\left(\mathrm{Cr}^{2+}, \mathrm{Fe}^{2+}\right)$ and $\left(\mathrm{Ti}^{3+}, \mathrm{Cu}^{2+}\right)$ are the pair of same magnetic moment.

Hence, the correct answer is option: 'D'.

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