Q2 / 160 · AP EAMCET 2007 · Chemistry
Which of the following pair of transition metal ions, have the same calculated values of magnetic moment?
- A$\mathrm{Ti}^{2+}$ and $\mathrm{V}^{2+}$
- B$\mathrm{Fe}^{2+}$ and $\mathrm{Cu}^{2+}$
- Correct answerC$\mathrm{Cr}^{2+}$ and $\mathrm{Fe}^{2+}$
- D$\mathrm{Co}^{2+}$ and $\mathrm{Ti}^{2+}$
Solution
$\mathrm{Cr}^{2+}(Z=24):[\mathrm{Ar}] 3 d^4 4 s^0 ; \quad 4 \quad$ unpaired electrons $\quad \mathrm{Fe}^{2+}(Z=26):[\mathrm{Ar}] 3 d^6 4 s^0$; 4 unpaired electrons $\mathrm{Cr}^{2+}$ and $\mathrm{Fe}^{2+}$ have same number of unpaired electrons, hence they have the same value of magnetic moment.
Hence, the correct answer is option: 'C'.