Q32 / 120 · VITEEE 2014 · Chemistry

Which of the following oxides is strongly basic?

  • A
    $\mathrm{Tl}_{2} \mathrm{O}$
  • Correct answer
    B
    $\mathrm{B}_{2} \mathrm{O}_{3}$
  • C
    $\mathrm{Al}_{2} \mathrm{O}_{3}$
  • D
    $\mathrm{Ga}_{2} \mathrm{O}_{3}$

Solution

On moving down the group, the nature of the oxides of group 13 elements changes from weakly acidic to amphoteric and amphoteric to basic. $\mathrm{Tl}_{2} \mathrm{O}$ in aqueous solution gives $\mathrm{TlOH}$ which soluble and a strong base.

Hence, the correct answer is option: 'B'.

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