Q5 / 51 · NTA Abhyas (JEE Main) 2020 · Chemistry · Biomolecules

Which of the following disaccharide will not reduce Tollen's reagent?

Figure
Figure

  • A
    P
  • Correct answer
    B
    Q
  • C
    P and Q both
  • D
    None of these

Solution

In (Q), it could be found that both the pyranose rings are attached through their reducing group, hence it will not be hydrolysed, and it can not reduce Tollen's reagent. So (Q) is not a reducing sugar, whereas in (P) one ring is hemiacetal which can be hydrolysed therefore it will be hydrolysed in solution and can reduce Tollen's reagent.

Figure
Figure

Hence, the correct answer is option: 'B'.

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