Q1 / 150 · MHT CET 2022 (07 Aug Shift 2) · Chemistry
Which of the following conversions need the reagent $\mathrm{Sn} / \mathrm{HCl}$ ?
- A$\mathrm{R}-\mathrm{CO}-\mathrm{NH}_2 \rightarrow \mathrm{R}-\mathrm{CH}_2-\mathrm{NH}_2$
- B$\mathrm{R}-\mathrm{C} \equiv \mathrm{N} \rightarrow \mathrm{R}-\mathrm{CH}_2-\mathrm{NH}_2$
- Correct answerC$\mathrm{R}-\mathrm{NO}_2 \rightarrow \mathrm{R}-\mathrm{NH}_2+2 \mathrm{H}_2 \mathrm{O}$
- D$\mathrm{R}-\mathrm{CO}-\mathrm{HN}_2 \rightarrow \mathrm{R}-\mathrm{NH}_2$
Solution
$\mathrm{R}-\mathrm{NO}_2 \stackrel{\mathrm{Sn} / \mathrm{HCl}}{\longrightarrow} \mathrm{R}-\mathrm{NH}_2+2 \mathrm{H}_2 \mathrm{O}$
Hence, the correct answer is option: 'C'.