Q43 / 62 · NTA Abhyas (JEE Main) 2020 · Chemistry · Haloalkanes and Haloarenes

Which of the following compounds will have the highest melting point here?

Figure

  • A
    III
  • Correct answer
    B
    II
  • C
    I
  • D
    They have equal melting point

Solution

Compound II is most symmetrical because it has both CH3 groups and Br atoms are apposite to each other therefore, it fits in the crystal lattice better than the other two isomers and hence it has high melting point.

Hence, the correct answer is option: 'B'.

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