Q41 / 150 · MHT CET 2025 (23 Apr Shift 1) · Chemistry
Which of the following compounds has high lattice enthalpy?
- ALiCl
- BNaCl
- Correct answerC$\mathrm{BeF}_2$
- D$\mathrm{CaCl}_2$
Solution
Lattice enthalpy depends on ionic charge magnitude and the sum of ionic radii, quantified by the relation $\text{Lattice Enthalpy} \propto \frac{|q_1 q_2|}{r_+ + r_-}$.
Among LiCl, NaCl, BeF$_2$, and CaCl$_2$, compounds with doubly charged cations (Be$^{2+}$ or Ca$^{2+}$) exhibit higher lattice enthalpy due to increased charge product. BeF$_2$ and CaCl$_2$ both have charge product $|(+2) \times (-1)| = 2$, whereas LiCl and NaCl have charge product $1$.
Be$^{2+}$ ($\approx 27$ pm) is smaller than Ca$^{2+}$ ($\approx 100$ pm), and F$^-$ ($\approx 133$ pm) is smaller than Cl$^-$ ($\approx 181$ pm), resulting in a notably smaller sum of radii for BeF$_2$ ($\approx 160$ pm) compared to CaCl$_2$ ($\approx 281$ pm).
Approximating the proportionality: for BeF$_2$, $\frac{2}{160} = \frac{1}{80}$; for LiCl, $\frac{1}{257}$. The value for BeF$_2$ is significantly larger, confirming it has the highest lattice enthalpy.
The answer is $\boxed{\text{C}}$.
Hence, the correct answer is option: 'C'.