Q5 / 160 · AP EAMCET 2021 (23 Aug Shift 1) · Chemistry

Which among the following isoelectronic species has the smallest size? $$ \mathrm{O}^{2-}, \mathrm{F}^{-}, \mathrm{Ne}, \mathrm{Na}^{+}, \mathrm{Mg}^{2+}, \mathrm{Al}^{3+}, \mathrm{Si}^{4+} $$

  • A
    $\mathrm{F}^{-}$
  • B
    $\mathrm{Ne}$
  • Correct answer
    C
    $\mathrm{Si}^{4+}$
  • D
    $\mathrm{Na}^{+}$

Solution

In isoelectronic species, the cation with greater +ve charge has smaller size. $\because \mathrm{Si}^{4+}$ has the smallest size.

Hence, the correct answer is option: 'C'.

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