Q36 / 150 · MHT CET 2023 (11 May Shift 1) · Chemistry

Which among the following halogens combines readily with metals to form metal halides with highest ionic character?

  • A
    Chlorine
  • B
    Bromine
  • C
    Iodine
  • Correct answer
    D
    Fluorine

Solution

Ionic character of metal halides decreases in the order $\mathrm{MF}>\mathrm{MCl}>\mathrm{MBr}>\mathrm{MI}$, where, $\mathrm{M}$ is a monovalent metal. Smaller the size of anion, greater is the ionic character (Fajan's rule). Therefore, fluorine forms metal halides with highest ionic character.

Hence, the correct answer is option: 'D'.

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