Q87 / 200 · NEET 2012 (Screening) · Chemistry

When $\mathrm{Cl}_2$ gas reacts with hot and concentrated sodium hydroxide solution, the oxidation number of chlorine changes from

  • A
    zero to +1 and zero to -5
  • Correct answer
    B
    zero to -1 and zero to +5
  • C
    zero to -1 and zero to +3
  • D
    zero to +1 and zero to -3

Solution

When chlorine gas reacts with hot and concentrated $\mathrm{NaOH}$ solution, it disproportionates into chloride $\left(\mathrm{Cl}^{-}\right)$and chlorate $\left(\mathrm{ClO}_3^{-}\right)$ions. Figure
In this process, oxidation number of chlorine changes from 0 to -1 and 0 to +5 . Note In disproportionation reactions, the same element undergoes oxidation as well as reduction.

Hence, the correct answer is option: 'B'.

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