Q87 / 200 · NEET 2012 (Screening) · Chemistry
When $\mathrm{Cl}_2$ gas reacts with hot and concentrated sodium hydroxide solution, the oxidation number of chlorine changes from
- Azero to +1 and zero to -5
- Correct answerBzero to -1 and zero to +5
- Czero to -1 and zero to +3
- Dzero to +1 and zero to -3
Solution
When chlorine gas reacts with hot and concentrated $\mathrm{NaOH}$ solution, it disproportionates into chloride $\left(\mathrm{Cl}^{-}\right)$and chlorate $\left(\mathrm{ClO}_3^{-}\right)$ions.

In this process, oxidation number of chlorine changes from 0 to -1 and 0 to +5 . Note In disproportionation reactions, the same element undergoes oxidation as well as reduction.

In this process, oxidation number of chlorine changes from 0 to -1 and 0 to +5 . Note In disproportionation reactions, the same element undergoes oxidation as well as reduction.
Hence, the correct answer is option: 'B'.