Q45 / 180 · JIPMER 2015 · Chemistry

When a mixture of 1-hexanol and hexanoic acid in diethyl ether is shaken with an aqueous $\mathrm{NaHCO}_3$ solution, then which of the following is right distribution? Figure

  • A
    In ether: hexanoic acid; In $\mathrm{NaHCO}_3$ : 1-hexanol
  • Correct answer
    B
    In ether: 1-hexanol ; In $\mathrm{NaHCO}_3$ : sodium hexanoate
  • C
    In ether: sodium hexaonate ; In $\mathrm{NaHCO}_3$ : 1hexanol
  • D
    In ether: 1-hexanol ; In $\mathrm{NaHCO}_3$ : hexanoic acid

Solution

Hexanoic acid is soluble in ether whereas alcohol is not soluble in $\mathrm{NaHCO}_3$ solution. Figure

Hence, the correct answer is option: 'B'.

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