Q59 / 200 · NEET 2008 (Screening) · Chemistry

What volume of oxygen gas $\left(\mathrm{O}_2\right)$ measured at $0^{\circ} \mathrm{C}$ and $1 \mathrm{~atm}$, is needed to burn completely $1 \mathrm{~L}$ of propane gas $\left(\mathrm{C}_3 \mathrm{H}_8\right)$ measured under the same conditions?

  • A
    $7 \mathrm{~L}$
  • B
    $6 \mathrm{~L}$
  • Correct answer
    C
    $5 \mathrm{~L}$
  • D
    $10 \mathrm{~L}$

Solution

Key Idea : Volume of a gas at $S T P=22.4 \mathrm{~L}$ $\begin{aligned} & \mathrm{C}_3 \mathrm{H}_8+5 \mathrm{O}_2 \longrightarrow 3 \mathrm{CO}_2+4 \mathrm{H}_2 \mathrm{O} \\ & 22.4 \mathrm{~L} \quad 5 \times 22.4 \mathrm{~L} \end{aligned}$ $\because$ To burn $22.4 \mathrm{~L} \mathrm{C}_3 \mathrm{H}_8$ the oxygen required is $=5 \times 22.4 \mathrm{~L}$ $\therefore$ To burn $1 \mathrm{LC}_3 \mathrm{H}_8$ the oxygen required will be $\begin{aligned} & =\frac{5 \times 22.4}{22.4} \\ & =5 \mathrm{~L} \end{aligned}$

Hence, the correct answer is option: 'C'.

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