Q26 / 150 · MHT CET 2025 (23 Apr Shift 2) · Chemistry

What type of overlap is involved in the formation of C-H bonds in acetylene molecules?

  • A
    $s p^3-s$
  • B
    $\mathrm{sp}^2-\mathrm{s}$
  • Correct answer
    C
    $s p-s$
  • D
    sp-sp

Solution

The carbon atoms in acetylene ($\mathrm{C_2 H_2}$) exhibit sp hybridization, resulting from two $σ$ bonds (one to hydrogen and one to carbon) and no lone pairs.

Each C–H $σ$ bond forms via overlap between a carbon sp hybrid orbital and hydrogen's 1s atomic orbital.

Reviewing the overlaps:

A) $sp^3$–$s$: characteristic of alkanes
B) $sp^2$–$s$: characteristic of alkenes
C) $sp$–$s$: correct for acetylene's C–H bonds
D) $sp$–$sp$: describes acetylene's C–C $σ$ bond

The C–H bonds in acetylene result from $sp$–$s$ overlap.

Hence, the correct answer is option: 'C'.

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