Q47 / 77 · NTA Abhyas (JEE Main) 2020 · Chemistry · Solid State

What are the coordination number (C.N.) of Ca2+ and F- ion in calcium fluoride CaF2 crystal structure?

  • A
    C.N. of Ca2+=4 and F-=8
  • B
    C.N. of Ca2+=6 and F-=6
  • C
    C.N. of Ca2+=8 and F-=8
  • Correct answer
    D
    C.N. of Ca2+=8 and F-=4

Solution

Each Ca2+ ion is surrounded by 8 F- ions and each F- ion by 4 Ca2+ ions. Thus, coordination number of Ca2+ is 8 and F- is 4.

Hence, the correct answer is option: 'D'.

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