Q13 / 50 · Manipal (MET) 2023 · Chemistry

Value of $E_2^0$ is $\qquad$ in the given diagram (ignore -ve sign) Figure

Correct answer: 0.77

Solution

$\Delta G_3=\Delta G_1+\Delta G_1$ $n_3 F E_3^{\circ}=n_1 F E_1^{\circ}+n_2 F E_2^{\circ}$ $3 \times 0.036=2 \times 0.439+1 \times E_2^{\circ}$ $\Rightarrow \quad E_2^{\circ}=0.108-0.878$ $=-0.77 \mathrm{~V}$

Hence, the correct answer is 0.77.

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