Q21 / 90 · JEE Main 2017 (02 Apr) · Chemistry

Two reactions A1 and A2 have identical pre-exponential factors. The activation energy of A1 is more than A2 by 10 kJ mol-1 . If k1 and k2 are the rate constants for reactions A1 and A2, respectively at 300 K, then ln⁡k2k1 is equal to

R=8.314 J mol-1K-1

  • A
    12
  • B
    6
  • Correct answer
    C
    4
  • D
    8

Solution

From Arrhenius equation

k=Ae-Ea/RT

k1=Ae-Ea1/RT

k2=Ae-Ea2/RT

lnk2k1=eEa1-Ea2/RT

ln⁡k2k1=Ea1-Ea2RT=10×10008.314×300=4

Hence, the correct answer is option: 'C'.

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