Q70 / 180 · AIIMS 2003 · Chemistry
Time required to deposit one millimole of aluminium metal by the passage of 9.65 amperes through aqueous solution of aluminium ion is
- A$30 \mathrm{~s}$
- Correct answerB$10 \mathrm{~s}$
- C$30,000 \mathrm{~s}$
- D$10,000 \mathrm{~s}$.
Solution
$ \mathrm{Al}^{3+}+3 e^{-} \rightarrow \mathrm{Al}$
For deposition of $1 \mathrm{~g}$ equivalent $\equiv 96500 \mathrm{C}$
For deposition of 1 millimole $\equiv 96.500 \mathrm{C}$
As $Q=I t \Rightarrow t=\frac{Q}{I}=\frac{96.5}{9.65}=10 \mathrm{~s}$
Hence, the correct answer is option: 'B'.