Q1 / 120 · VITEEE 2019 · Chemistry

The work done in ergs for the reversible expansion of one mole of an ideal gas from a volume of 10 litres to 20 litres at $25^{\circ} \mathrm{C}$ is

  • A
    $2.303 \times 298 \times 0.082 \log 2$
  • Correct answer
    B
    $298 \times 10^{7} \times 8.31 \times 2.303 \log 2$
  • C
    $2.303 \times 298 \times 0.082 \log 0.5$
  • D
    $8.31 \times 10^{7} \times 298-2.303 \log 0.5$

Solution

$$ \begin{aligned} \mathrm{W} &=2.303 \mathrm{nRT} \log \frac{\mathrm{V}_{2}}{\mathrm{~V}_{1}} \\ &=2.303 \times 1 \times 8.314 \times 10^{7} \times 298 \log \frac{20}{10} \\ &=298 \times 10^{7} \times 8.31 \times 2.303 \log 2 \end{aligned} $$

Hence, the correct answer is option: 'B'.

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