Q77 / 180 · NEET 2015 (Phase 2) · Chemistry

The variation of the boiling points of the hydrogen halides is in the order HF>HI>HBr>HCl . Which of the following option explains the higher boiling point of hydrogen fluoride?

  • A
    The electronegativity of fluorine is much higher than for other elements in the group.
  • Correct answer
    B
    There is strong hydrogen bonding between HF molecules.
  • C
    The bond energy of HF molecules is greater than in other hydrogen halides.
  • D
    The effect of nuclear shielding is much reduced in fluorine which polarizes the HF molecule.

Solution

Due to strong H-bonding in HF molecule, boiling point is highest for HF .

HF>HI>HBr>HCl

Hence, the correct answer is option: 'B'.

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