Q138 / 160 · AP EAMCET 2019 (23 Apr Shift 1) · Physics
The specific heat capacities of an ideal gas at the constant pressure and at constant volume are \(620 \mathrm{Jkg}^{-1} \mathrm{~K}^{-1}\) and \(420 \mathrm{Jkg}^{-1} \mathrm{~K}^{-1}\) respectively. The density of the gas at STP is approximately,
- A\(2.88 \mathrm{kgm}^{-3}\)
- B\(4.86 \mathrm{kgm}^{-3}\)
- C\(3.88 \mathrm{kgm}^{-3}\)
- Correct answerD\(1.86 \mathrm{kgm}^{-3}\)
Solution
Given, specific heat capacity of a gas at constant pressure, \(C_p=620 \mathrm{~J} \mathrm{~kg}^{-1} \mathrm{~K}^{-1}\) and specific heat capacity of gas at constant volume, \(C_V=420 \mathrm{~J} \mathrm{~kg}^{-1} \mathrm{~K}^{-1}\)
\(\because\) Molar specific heat of gas at constant pressure and constant volume are given by
\(\therefore \quad C_p{ }^{\prime}=m C_p=m(620)\)
and \(\quad C_V{ }^{\prime}=m C_v=m(420)\)
As we know that,
\(\because \quad C_p{ }^{\prime}-C_V{ }^{\prime}=R\)
[Here, \(R\) = universal gas constant]
\(\begin{aligned}
m[620-420] & =R \\
\Rightarrow \quad m & =\frac{R}{200} \qquad \ldots (i)
\end{aligned}\)
Now, ideal gas equation,
\(p V=\mu R T\)
where, \(\mu=\) number of moles of gas
or
\(\begin{aligned}
& p V=R T \quad[\because \text { for } 1 \text { mole, } \mu=1] \\
& \therefore \quad p m=\rho R T \quad\left[\because \text { density, } \rho=\frac{m}{V}\right] \\
& 10^5 \times \frac{R}{200}=\rho R(273) \quad \text { [From Eq. (i)] } \\
& \rho=1.85 \mathrm{Kg}-\mathrm{m}^{-3}
\end{aligned}\)
Hence, the option (d) is correct.
Hence, the correct answer is option: 'D'.