Q132 / 160 · WBJEE 2015 · Physics

The rms speed of oxygen is $v$ at a particular temperature. If the temperature is doubled and oxygen molecules dissociate into oxygen atoms, the rms speed becomes

  • A
    v
  • B
    $\sqrt{2} v$
  • Correct answer
    C
    $2v$
  • D
    $4 v$

Solution

As the rms speed is given by $$ \begin{aligned} & v_{\text {rms }}=\sqrt{\frac{3 R T}{M}}{V_{\text {ms }}} \propto \sqrt{\frac{T}{M}} \end{aligned} $$ When temperature is doubled and molecules dissociates into atoms, then $$ \begin{aligned} \frac{v_{\mathrm{rms}_{1}}}{v_{\mathrm{rms}_{2}}} &=\frac{\sqrt{\frac{T}{M}}}{\sqrt{\frac{2 T}{M / 2}}}=\frac{\sqrt{\frac{T}{M}}}{\sqrt{\frac{4 T}{M}}} \\ &=\frac{\sqrt{T}}{\sqrt{4 T}}=\frac{1}{2} \end{aligned} $$ If $v_{\mathrm{rms}},$ is $v,$ then $v_{\mathrm{rms}_{2}}$ will be $2 v$.

Hence, the correct answer is option: 'C'.

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