Q13 / 180 · KCET 2022 · Chemistry

The rise in boiling point of a solution containing $1.8 \mathrm{~g}$ of glucose in $100 \mathrm{~g}$ of solvent is $0.1^{\circ} \mathrm{C}$. The molal elevation constant of the liquid is

  • Correct answer
    A
    $1 \mathrm{~K} \mathrm{~kg} / \mathrm{mol}$
  • B
    $2 \mathrm{~K} \mathrm{~kg} / \mathrm{mol}$
  • C
    $10 \mathrm{~K} \mathrm{~kg} / \mathrm{mol}$
  • D
    $0.1 \mathrm{~K} \mathrm{~kg} / \mathrm{mol}$

Solution

Given, amount of glucose $(w)=1.8 \mathrm{~g}$ Amount of solvent $(W)=100 \mathrm{~g}$ $\Delta T_b=0.1^{\circ} \mathrm{C}$ Molecular mass of glucose $=180$ Molal elevation constant of the liquid, $\Delta T_b=0.1^{\circ} \mathrm{C}$ We know that, $$ \begin{aligned} K_b & =\frac{\Delta T_b \times m \times W}{1000 \times w} \\ & =\frac{0.1 \times 180 \times 100}{1000 \times 1.8}=1 \mathrm{~K} \mathrm{~kg} / \mathrm{mol} \end{aligned} $$

Hence, the correct answer is option: 'A'.

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