Q27 / 90 · JEE Main 2021 (27 Aug Shift 1) · Chemistry

The reaction that occurs in a breath analyser, a device used to determine the alcohol level in a person's blood stream is

2 K2Cr2O7+8H2SO4+3C2H6O→2Cr2SO43+3C2H4O2+2 K2SO4+11H2O

If the rate of appearance of Cr2SO43 is 2.67 mol min-1 at a particular time, the rate of disappearance of C2H6O at the same time is mol min-1. (Nearest integer)

Correct answer: 4

Solution

13-dC2H6Odt=12dCr2SO43dt

13 (Rate of disappearance of C2H6O=12 (Rate of disappearance of Cr2SO43

Rate of disappearance of C2H6O=2.67 mol/min×32=4.005 mol/min

Hence, the correct answer is 4.

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