Q31 / 160 · TS EAMCET 2021 (05 Aug Shift 2) · Chemistry

The reaction of aqueous NiH2062+ Is performed by the addition of a bidentate ligand ethane-1, 2, diamine (en)
Match the following
  NiH2O62+: en molar ratio   Colour of the product
A 1 : 1 I Pale blue
B 1 : 2 II Blue / Purple
C 1 : 3 III Violet
D   IV Green

The correct match is

  • Correct answer
    A
    A B C
    I II III
  • B
    A B C
    II III IV
  • C
    A B C
    III I II
    .
  • D
    A B C
    IV I III

Solution

According to the question, in case of [MX6], M=Ni, X= weak field ligand or strong field ligand, Nickel is always forms sp3d2 Hybridisation. Ni+2=3d8,4s0. In this condition Nickel has two -unpair electrons. Due to this it shows green colour.

Hence, the correct answer is option: 'A'.

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