Q9 / 160 · TS EAMCET 2021 (04 Aug Shift 2) · Chemistry

The products P and Q of the following reaction, respectively, are a S8( s)+bNaOHaq⟶Paq+qQaq+rH2O

  • Correct answer
    A
    Na2 S; Na2 S2O3
  • B
    Na; Na2S2O3
  • C
    Na; Na2 S
  • D
    SO2; Na2SO4

Solution

We know that S8 has crown-shaped ring structure while NaOH is a strong alkali and when sulphur reacts with hot aqueous alkali hydroxide it forms sodium sulfide and thiosulphate species.

So, the balanced chemical equation is represented as 

S8 + 12 NaOH → 4 Na2S + 2 Na2S2O3 + 6 H2O

Hence, the obtained products are Na2S & Na2S2O3

Hence, the correct answer is option: 'A'.

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