Q36 / 160 · AP EAMCET 2022 (08 Jul Shift 1) · Chemistry
The product(s) formed when toluene is reacted with $\mathrm{Cl}_2$ in presence of $\mathrm{Fe}$ in dark is/are
- Correct answerA

- B

- C

- D

Solution
In presence of UV light with same reagent, $\mathrm{C}_{\mathrm{sp}^3}-\mathrm{H}$ bond breaks down and forms free radical resulting into $\mathrm{C}_{\mathrm{sn}_3}-\mathrm{Cl}$ bond formation.
Hence, the correct answer is option: 'A'.