Q25 / 160 · TS EAMCET 2003 · Chemistry
The product obtained at anode when $50 \%$ $\mathrm{H}_2 \mathrm{SO}_4$ aqueous solution is electrolysed using platinum electrodes is :
- A$\mathrm{H}_2 \mathrm{SO}_3$
- Correct answerB$\mathrm{H}_2 \mathrm{~S}_2 \mathrm{O}_8$
- C$\mathrm{O}_2$
- D$\mathrm{H}_2$
Solution
$50 \% \mathrm{H}_2 \mathrm{SO}_4$ aqueous solution can be electrolysed by using Pt electrodes as $2 \mathrm{H}_2 \mathrm{SO}_4 2 \mathrm{HSO}_4^{-}+2 \mathrm{H}^{+}$
$2 \mathrm{HSO}_4^{-} \longrightarrow \mathrm{H}_2 \mathrm{~S}_2 \mathrm{O}_8+2 e^{-}$(at anode)
Hence, the correct answer is option: 'B'.