Q34 / 160 · TS EAMCET 2021 (04 Aug Shift 2) · Chemistry

The possible final products R and S of the following reaction sequence are
Figure

  • A
    R S
    Figure Figure
  • B
    R S
    Figure Figure
  • Correct answer
    C
    R S
    Figure Figure
  • D
    R S
    Figure Figure

Solution

When Bromine react with toluene (in which methyl group is ring activating and para directing group according to resonance) in the presence of Fe/dark then product P which is obtained is o−bromotoluene.and product Q is p−bromotoluene and this reaction is called electrophilic substitution reaction.

Now, when o−bromotoluene react with Mg/ether in the presence of water this will lead to formation of phenol and when it is further treated with HCHO then we will be left with o-hydroxymethylphenol and p-hydroxymethylphenol that willbe our final product R and S.

FigureFigure

Hence, the correct answer is option: 'C'.

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