Q53 / 180 · NEET 2019 (Odisha) · Chemistry

The oxidation state of $\mathrm{Cr}$ in $\mathrm{CrO}_5$ is

  • A
    -6
  • B
    +12
  • Correct answer
    C
    +6
  • D
    +4

Solution

$\text {The structure of } \mathrm{CrO}_5 \text { is }$ Figure
Oxidation state of $\mathrm{Cr}$ is +6 due to the presence of two peroxide linkages, which can be calculated as. In $\mathrm{CrO}\left(\mathrm{O}_2\right)_2$, let the oxidation state of $\mathrm{Cr}$ be $\mathrm{x}$ $\begin{aligned} \mathrm{x}+(-1) 4+(-2) & =0 \\ \mathrm{x}-6 & =0 \\ \mathrm{x} & =+6 \end{aligned}$

Hence, the correct answer is option: 'C'.

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