Q35 / 180 · AIIMS 2007 · Chemistry
The order of bond length is
- Correct answerA\(\mathrm{O}_2 < \mathrm{O}_3 < \mathrm{O}_2{ }^{2-}\)
- B\(\mathrm{O}_2 < \mathrm{O}_2{ }^{2-} < \mathrm{O}_3\)
- C\(\mathrm{O}_2{ }^{2-} < \mathrm{O}_3 < \mathrm{O}_2\)
- D\(\mathrm{O}_2=\mathrm{O}_2{ }^{2-} > \mathrm{O}_3\).
Solution
Ozone molecule is V-shaped with \(\mathrm{O}-\mathrm{O}\) bond length \(1.278 Å\).

The bond length is intermediate between that for a single bond \(\left(1.48 Å\right.\) as in \(\left.\mathrm{H}_2 \mathrm{O}_2\right)\) and for a double bond (1.21 \(Å\) as in \(\mathrm{O}_2\)).

The bond length is intermediate between that for a single bond \(\left(1.48 Å\right.\) as in \(\left.\mathrm{H}_2 \mathrm{O}_2\right)\) and for a double bond (1.21 \(Å\) as in \(\mathrm{O}_2\)).
Hence, the correct answer is option: 'A'.