Q35 / 180 · AIIMS 2007 · Chemistry

The order of bond length is

  • Correct answer
    A
    \(\mathrm{O}_2 < \mathrm{O}_3 < \mathrm{O}_2{ }^{2-}\)
  • B
    \(\mathrm{O}_2 < \mathrm{O}_2{ }^{2-} < \mathrm{O}_3\)
  • C
    \(\mathrm{O}_2{ }^{2-} < \mathrm{O}_3 < \mathrm{O}_2\)
  • D
    \(\mathrm{O}_2=\mathrm{O}_2{ }^{2-} > \mathrm{O}_3\).

Solution

Ozone molecule is V-shaped with \(\mathrm{O}-\mathrm{O}\) bond length \(1.278 Å\). Figure
The bond length is intermediate between that for a single bond \(\left(1.48 Å\right.\) as in \(\left.\mathrm{H}_2 \mathrm{O}_2\right)\) and for a double bond (1.21 \(Å\) as in \(\mathrm{O}_2\)).

Hence, the correct answer is option: 'A'.

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