Q4 / 90 · JEE Main 2022 (25 Jul Shift 2) · Chemistry

The molar conductivity of a conductivity cell filled with 10 moles of 20 mL  NaCl solution is Λm1 and that of 20 moles another identical cell heaving 80 mL NaCl solution is Λm2, The conductivities exhibited by these two cells are same.

The relationship between Λm2 and Λm1 is

  • Correct answer
    A
    Λm2=2Λm1
  • B
    Λm2=Λm1/2
  • C
    Λm2=Λm1
  • D
    Λm2=4Λm1

Solution

Λm=κ×1000M

⇒Λm∝1M

Λm1Λm2=M2M1=20801020=14×21=12

⇒Λm2=2Λm1

Hence, the correct answer is option: 'A'.

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