Q19 / 160 · AP EAMCET 2022 (06 Jul Shift 2) · Chemistry

The major products $P$ and $Q$ of the following reactions respectively are I. $n$-pentyl bromide $\xrightarrow{\mathrm{Zn} / \mathrm{H}^{+}} P$ II. $n$-pentyl bromide $\xrightarrow[\text { Dry ether }]{\mathrm{Na}} Q$

  • Correct answer
    A
    pentane; decane
  • B
    pent-1-en; decane
  • C
    pentane ; pentane
  • D
    pentane : 1-decene

Solution

When $n$-pentyl bromide reacts with $\mathrm{Zn}$, $\mathrm{Br}$ atom is substituted by $\mathrm{H}$-atom to form pentane. But when $n$-pentyl bromide reacts with $\mathrm{Na}$ and dry ether, it undergoes Wurtz reaction and decane is formed. Figure

Hence, the correct answer is option: 'A'.

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