Q47 / 180 · COMEDK 2023 (Memory Based) · Chemistry

The ion that is isoelectronic with $\mathrm{CO}$ is

  • A
    $\mathrm{O}_2^{+}$
  • Correct answer
    B
    $\mathrm{CN}^{-}$
  • C
    $\mathrm{O}_2^{-}$
  • D
    $\mathrm{N}_2^{+}$

Solution

$\mathrm{CN}^{-}$is isoelectronic to $\mathrm{CO}$ as they have same number of electrons. Number of electrons in the given species is as follows, $\begin{aligned} & \mathrm{CO}=6+8=14 \\ & \mathrm{O}_2^{-}=16+1=17 \\ & \mathrm{~N}_2^{+}=14-1=13 \\ & \mathrm{O}_2^{+}=16-1=15 \\ & \mathrm{CN}^{-}=6+7+1=14 \end{aligned}$

Hence, the correct answer is option: 'B'.

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