Q18 / 150 · MHT CET 2019 (Shift 1) · Chemistry

The integrated rate equation for first order reaction, A→ product, is

  • A
    k=1tlnAtA0
  • B
    k=2303t+log10A0At
  • Correct answer
    C
    k=1tlnA1A0.
  • D
    k=2303 tlog10A0At

Solution

The integrated rate equation for first order
Reaction, A→ product is k=1t In AtA0.
For 1st order reactions, R→P
Rate = -dRdt=k·R
On integrating this equation, we get
In R=-kt+l                        ...i
At t=0,R=R0=-k×0+l
In R0=l
Substituting the value of l in (i) and on rearrangement, we get
In R=-kt+InR0
And, k=1tInR0R

Hence, the correct answer is option: 'C'.

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