Q17 / 180 · KCET 2015 · Chemistry

The hydrolysis of optically active \( 2 \)-bromobutane with aqueous \( \mathrm{NaOH} \) result in the formation of

  • A
    \( (+) \) butan-2-ol
  • B
    (-) butan-2-ol
  • C
    ( \( \pm \) ) butan-1-ol
  • Correct answer
    D
    ( \( \pm \) ) butan-2-ol

Solution

2-Bromobutane is a secondary alkyl halide, therefore, hydrolysis will proceed through \( S_{N} 1 \) mechanisms, hence, racemic
mixture will be formed, that is, (±) butan-2-ol.
Figure
Figure
(+) Butan-2-ol
(-) Butan-2-ol

Hence, the correct answer is option: 'D'.

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