Q12 / 90 · JEE Main 2016 (09 Apr Online) · Chemistry

The group of molecules having identical shape is:

A
$P C l_{5}, I F_{5}, X e O_{2} F_{2}$
B
$B F_{3}, P C l_{3}, X e O_{3}$
C
$S F_{4}, X e F_{4}, C C l_{4}$
Correct answer
D
$C l F_{3}, X e O F_{2}, X e F_{3}^{+}$

Solution

All molecules have same hybridisation i.e

{sp}^{3} d

and have similar structure, the T-shaped. So,they are isostructural

Hence, the correct answer is option: 'D'.

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