Q54 / 180 · NEET 2015 (Phase 2) · Chemistry
The formation of the oxide ion, , from oxygen atom requires first an exothermic and then an endothermic step as shown in below:
Thus process of formation of in gas phase is unfavourable though is isoelectronic with neon. It is due to the fact that,
Thus process of formation of in gas phase is unfavourable though is isoelectronic with neon. It is due to the fact that,
- Correct answerAElectron repulsion outweighs the stability gained by achieving noble gas configuration.
- BIon has comparatively smaller size than oxygen atom.
- COxygen is more electronegative.
- DAddition of electron in oxygen results in larger size of the ion.
Solution
Due to the fact that electron repulsion outweighs the stability gained by achieving noble gas configuration, formation of in gas phase is unfavourable though is isoelectronic with neon. When an electron is added to anion, there is strong electrostatic repulsion between the two negative charges. Due to this, the second electron gain enthalpy of oxygen is positive.
Hence, the correct answer is option: 'A'.