Q6 / 90 · JEE Main 2022 (25 Jul Shift 2) · Chemistry

The first ionization enthalpies of Be, B, N and O follow the order

  • Correct answer
    A
    B<Be<O<N
  • B
    O<N<B<Be
  • C
    Be<B<N<O
  • D
    B<Be<N<O

Solution

The ionisation enthalpy increases as we go from left to right in a period, while it decreases as we come down a group. So according to this, the order will be Be<B<C<N<O. But there are two exceptions, in the case of Be and N because of the highly stable 2s2 (completely filled orbital) and 2s22p3 (half-filled orbital 2p3) valence configuration. Due to this, the correct order is:
B<Be<C<O<N.

Hence, the correct answer is option: 'A'.

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