Q21 / 180 · KCET 2009 · Chemistry

The electrophile involved in the sulphonation of benzene is

  • A
    $\mathrm{SO}_{3}^{+}$
  • B
    $\mathrm{SO}_{3}^{2-}$
  • C
    $\mathrm{H}_{3}^{+} \mathrm{O}$
  • Correct answer
    D
    $\mathrm{SO}_{3}$

Solution

The electrophile involved in the sulphonation of benzene is $\mathrm{SO}_{3}$. $$ 2 \mathrm{H}_{2} \mathrm{SO}_{4} \longrightarrow \mathrm{SO}_{3}+\mathrm{H}_{3} \mathrm{O}^{+}+\mathrm{HSO}_{4}^{-} $$

Hence, the correct answer is option: 'D'.

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