Q14 / 125 · BITSAT 2014 · Chemistry
The correct order of increasing $\mathrm{C}-\mathrm{O}$ bond length $\mathrm{CO}, \mathrm{CO}_{3}^{2-}, \mathrm{CO}_{2}$ is:
- Correct answerA$\mathrm{CO}<\mathrm{CO}_{2}<\mathrm{CO}_{3}^{2-}$
- B$\mathrm{CO}_{2}<\mathrm{CO}_{3}^{2-}<\mathrm{CO}$
- C$\mathrm{CO}<\mathrm{CO}_{3}^{2-}<\mathrm{CO}_{2}$
- D$\mathrm{CO}_{3}^{2-}<\mathrm{CO}_{3}<\mathrm{CO}$
Solution
$\mathrm{C} \equiv \mathrm{Ohas}$ lowest bond length due to highest bond order. $\mathrm{O}=\mathrm{C}=\mathrm{O}$ has second lowest bond length due to double bond.

has highest has bond length due to lowest bond order which is due to resonance.

has highest has bond length due to lowest bond order which is due to resonance.
Hence, the correct answer is option: 'A'.