Q14 / 125 · BITSAT 2014 · Chemistry

The correct order of increasing $\mathrm{C}-\mathrm{O}$ bond length $\mathrm{CO}, \mathrm{CO}_{3}^{2-}, \mathrm{CO}_{2}$ is:

  • Correct answer
    A
    $\mathrm{CO}<\mathrm{CO}_{2}<\mathrm{CO}_{3}^{2-}$
  • B
    $\mathrm{CO}_{2}<\mathrm{CO}_{3}^{2-}<\mathrm{CO}$
  • C
    $\mathrm{CO}<\mathrm{CO}_{3}^{2-}<\mathrm{CO}_{2}$
  • D
    $\mathrm{CO}_{3}^{2-}<\mathrm{CO}_{3}<\mathrm{CO}$

Solution

$\mathrm{C} \equiv \mathrm{Ohas}$ lowest bond length due to highest bond order. $\mathrm{O}=\mathrm{C}=\mathrm{O}$ has second lowest bond length due to double bond. Figure
has highest has bond length due to lowest bond order which is due to resonance.

Hence, the correct answer is option: 'A'.

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