Q12 / 90 · JEE Main 2023 (29 Jan Shift 1) · Chemistry

The correct order of hydration enthalpies is

(A) K+
(B) Rb+
(C) Mg2+
(D) Cs+
(E) Ca2+

Choose the correct answer from the options given below:

  • A
    C > A > E > B > D
  • B
    E > C > A > B > D
  • C
    C > E > A > D > B
  • Correct answer
    D
    C > E > A > B > D

Solution

The hydration enthalpy of alkali metal ions decreases with an increase in ionic sizes.

So, the order is: Li+ > Na+ >  K+ > Rb+ > Cs+

Like alkali metal ions, the hydration enthalpies of alkaline earth metal ions decrease with an increase in ionic size down the group.

So, the order is: Be2+ > Mg2+ > Ca2+ > Sr2+ > Ba2+ 

The hydration enthalpies of alkaline earth metal ions are larger than those of alkali metal ions. 

So, the correct order is: Mg2+ > Ca2+ > K+ > Rb+ > Cs+ 

 

Hence, the correct answer is option: 'D'.

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