Q34 / 200 · WBJEE 2013 · Chemistry

The correct order of acid strength of the following substituted phenols in water at $28^{\circ} \mathrm{C}$ is

  • A
    $p$-nitrophenol $ < $ p-fluorophenol $ < $ p-chlorophenol
  • B
    $p$-chlorophenol $ < $ p-fluorophenol $ < $ p-nitrophenol
  • Correct answer
    C
    p-fluorophenol $ < $ p-chlorophenol $ < $ p-nitrophenol
  • D
    $p$-flurophenol $ < $ p-nitrophenol $ < p$-chlorophenol

Solution

The order of electron withdrawing tendency from benzene ring i.e.. $$ -F < -C l < -N O_{2} $$ $\therefore$ Correct order of acidic strength of substituted phenols will beFigure

Hence, the correct answer is option: 'C'.

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