Q89 / 200 · NEET 2005 · Chemistry
The correct order of acid strength is:
- A$\mathrm{HClO}_4 < \mathrm{HClO}_3 < \mathrm{HClO}_2 < \mathrm{HClO}$
- Correct answerB$\mathrm{HClO} < \mathrm{HClO}_2 < \mathrm{HClO}_3 < \mathrm{HClO}_4$
- C$\mathrm{HClO}_4 < \mathrm{HClO}^2 < \mathrm{HClO}_2 < \mathrm{HClO}_3$
- D$\mathrm{HClO}_2 < \mathrm{HClO}_3 < \mathrm{HClO}_4 < \mathrm{HClO}$
Solution
Oxygen is more electronegative than chlorine. With an increase in the number of $\mathrm{O}$ atoms attached to $\mathrm{Cl}$, more electrons are pulled away from $\mathrm{O}-\mathrm{H}$ bond and weaker becomes the $\mathrm{O}-\mathrm{H}$ bond. This increases the acid strength. The decreasing order of acidic strength is $\mathrm{HClO} < \mathrm{HClO}_2 < $ $\mathrm{HClO}_3 < \mathrm{HClO}_4$

Hence, the correct answer is option: 'B'.