Q89 / 200 · NEET 2005 · Chemistry

The correct order of acid strength is:

  • A
    $\mathrm{HClO}_4 < \mathrm{HClO}_3 < \mathrm{HClO}_2 < \mathrm{HClO}$
  • Correct answer
    B
    $\mathrm{HClO} < \mathrm{HClO}_2 < \mathrm{HClO}_3 < \mathrm{HClO}_4$
  • C
    $\mathrm{HClO}_4 < \mathrm{HClO}^2 < \mathrm{HClO}_2 < \mathrm{HClO}_3$
  • D
    $\mathrm{HClO}_2 < \mathrm{HClO}_3 < \mathrm{HClO}_4 < \mathrm{HClO}$

Solution

Oxygen is more electronegative than chlorine. With an increase in the number of $\mathrm{O}$ atoms attached to $\mathrm{Cl}$, more electrons are pulled away from $\mathrm{O}-\mathrm{H}$ bond and weaker becomes the $\mathrm{O}-\mathrm{H}$ bond. This increases the acid strength. The decreasing order of acidic strength is $\mathrm{HClO} < \mathrm{HClO}_2 < $ $\mathrm{HClO}_3 < \mathrm{HClO}_4$Figure

Hence, the correct answer is option: 'B'.

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