Q1 / 54 · JEE Advanced 2018 (Paper 2) · Chemistry
The correct option(s) regarding the complex :-
(en ) is (are)
(en ) is (are)
- Correct answerAIt has two geometrical isomers
- Correct answerBIt will have three geometrical isomers if bidentate 'en' is replaced by two cyanide ligands
- CIt is paramagnetic
- Correct answerDIt absorbs light at longer wavelength as compared to
Solution
complex is type of have two G.I.

If (en) is replaced by two cyanide ligand, complex will be type of and have 3 G.I.

on central metal with SFL therefore it is dimagnetic in nature.
Complex have lesser value than therefore complex absorbs longer wavelength for d-d transition

If (en) is replaced by two cyanide ligand, complex will be type of and have 3 G.I.

on central metal with SFL therefore it is dimagnetic in nature.
Complex have lesser value than therefore complex absorbs longer wavelength for d-d transition
Hence, the correct answer is options: 'A', 'B', 'D'.