Q86 / 180 · NEET 2018 · Chemistry

The compound A on treatment with Na gives B, and with PCl5 gives C. B and C react together to give diethyl ether. A, B and C are in the order

  • A
    C2H5Cl,C2H6,C2H5OH
  • B
    C2H5OH,C2H5Cl,C2H5ONa
  • C
    C2H5OH,C2H6,C2H5Cl
  • Correct answer
    D
    C2H5OH,C2H5ONa,C2H5Cl

Solution

Figure

The Williamson ether synthesis is an organic reaction, forming an ether from an organohalide and a deprotonated alcohol. This reaction was developed by Alexander Williamson in 1850. Typically it involves the reaction of an alkoxide ion with a primary alkyl halide via an SN2 reaction.

Figure

Hence, the correct answer is option: 'D'.

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