Q23 / 90 · JEE Main 2012 (26 May Online) · Chemistry

The complex ion $\left[\operatorname{Pt}\left(\mathrm{NO}_2\right)(\mathrm{Py})\left(\mathrm{NH}_3\right)\left(\mathrm{NH}_2 \mathrm{OH}\right)\right]^{+}$ will give

  • A
    2 isomers (Geometrical)
  • Correct answer
    B
    3 isomers (Geometrical)
  • C
    6 isomers (Geometrical)
  • D
    4 isomers (Geometrical)

Solution

Complexes of the type $\mathrm{M}_{A B C D}$ may exist in three isomeric form. Similarily $\left.\left(\mathrm{Pt}\left(\mathrm{NO}_2\right)(\mathrm{Py})\left(\mathrm{NH}_3\right)\left(\mathrm{NH}_2 \mathrm{OH}\right)\right]^{+}\right)$may exist in three isomeric form. Figure

Hence, the correct answer is option: 'B'.

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