Q29 / 180 · COMEDK 2022 · Chemistry

The colour of $\mathrm{CrO}_4^{2-}$ changes to $\mathrm{Cr}_2 \mathrm{O}_7^{2-}$ is

  • Correct answer
    A
    yellow to orange
  • B
    orange to yellow
  • C
    yellow to blue
  • D
    orange to blue

Solution

The chromate ion $\mathrm{CrO}_4^{2-}$ is yellow in aqueous solution. In an acidic medium, the chromate ion undergoes dimerization to form the dichromate ion $\mathrm{Cr}_2 \mathrm{O}_7^{2-}$, which is orange in color.

The equilibrium reaction is given by: $2\mathrm{CrO}_4^{2-} + 2\mathrm{H}^{+} \rightleftharpoons \mathrm{Cr}_2 \mathrm{O}_7^{2-} + \mathrm{H}_2 \mathrm{O}$.

Thus, the color change observed is from yellow to orange.

Answer: yellow to orange

Hence, the correct answer is option: 'A'.

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