Q4 / 160 · TS EAMCET 2022 (18 Jul Shift 2) · Chemistry

The change in enthalpy ΔH in kJmol-1 for the reaction is Mg+2 F→MgF2

Given: EA of F=328 kJ mol-1,IE1 of Mg=737 kJ mol-1,IE2 of Mg=1451 kJ mol-1

  • A
    3064
  • B
    876
  • C
    1860
  • Correct answer
    D
    1532

Solution

The enthalpy change accompanying a reaction is called the reaction enthalpy.

Enthalpy of a reaction depends on the conditions under which a reaction is carried out.

The change in enthalpy of the reactionMg+2 F→MgF2 is calculated as given below

Mgg→Mgg+2+2e-, ∆H=∆HI.E1+∆HI.E22F+2e-→2F-,  ∆H=2∆HE.A-------------------Mgg+2F→Mgg+2+2F-, ∆H=∆HI.E1+∆HI.E2+2∆HE.A∆H=737+1451+2(-328)       =1532kJ mol-1

 

Hence, the correct answer is option: 'D'.

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